3. Non- ribosomal peptide synthetases and polyketide synthetases are responsible for the biosynthesis of a vast range of natural products, some of which have biotechnological importance. Compare and contrast these enzymes, paying particular attention to amino acid substrate selectivity in non-ribosomal peptide synthesis, as well as the essential requirement for apo-enzyme activation, if both types of enzyme, by post-translational modification. use diagrams and chemical structures where appropriate to support your answer.
4.
Discuss in detail gliotoxin biosynthesis, functionality and self- protection mechanisms in fungi. Your answer should include details if genes and enzymes involved in these processes, the in Vivo role of the biomolecule, along with the research techniques used to reveal gene function. Use diagrams and chemical structures where appropriate to support your answer.
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